Carbon Tetrabromide: An Efficient Catalyst for Regioselective Ring Opening of Epoxides with Alcohols and Water

ABSTRACT Epoxides undergo rapid ring opening with a range of alcohols in the presence of catalytic amount of carbon tetrabromide under mild and convenient conditions to afford the corresponding β-alkoxy alcohols and 1,2-diols in high yields with high regioselectivity.

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Veröffentlicht in:Synthesis (Stuttgart) 2005-11, Vol.2005 (17), p.2897-2900
Hauptverfasser: Yadav, J. S., Reddy, B. V., Harikishan, K., Madan, Ch, Narsaiah, A. V.
Format: Artikel
Sprache:eng
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Zusammenfassung:ABSTRACT Epoxides undergo rapid ring opening with a range of alcohols in the presence of catalytic amount of carbon tetrabromide under mild and convenient conditions to afford the corresponding β-alkoxy alcohols and 1,2-diols in high yields with high regioselectivity.
ISSN:0039-7881
1437-210X
DOI:10.1055/s-2005-918422