Hydrothiophosphorylation of Vinyl Sulfoxides: First Examples

Hydrothiophosphorylation of Vinyl Sulfoxides: First Examples

ABSTRACT The first examples of facile hydrothiophosphorylation of organyl vinyl sulfoxides are described. Nucleophilic addition of P,S-ambident secondary phosphine sulfides 1 and 2 to organyl vinyl sulfoxides 3-6 with potassium hydroxide at room temperature proceeds chemo- and regioselectively to gi...

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Veröffentlicht in:Synthesis (Stuttgart) 2005-11, Vol.2005 (18), p.3103-3106
Hauptverfasser: Gusarova, Nina K., Bogdanova, Maria V., Ivanova, Nina I., Chernysheva, Nataliya A., Sukhov, Boris G., Sinegovskaya, Lidiya M., Kazheva, Olga N., Alexandrov, Grigorii G., D’yachenko, Oleg A., Trofimov, Boris A.
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Sprache:eng
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Zusammenfassung:ABSTRACT The first examples of facile hydrothiophosphorylation of organyl vinyl sulfoxides are described. Nucleophilic addition of P,S-ambident secondary phosphine sulfides 1 and 2 to organyl vinyl sulfoxides 3-6 with potassium hydroxide at room temperature proceeds chemo- and regioselectively to give the corresponding bis(2-organylethyl)[2-(organylsulfinyl)ethyl]phosphine sulfides 7A-E in high isolated yields.
ISSN:0039-7881
1437-210X
DOI:10.1055/s-2005-918408