Palladium-Catalyzed Reaction of Bicyclic Hydrazines with Allyl- and Arylstannanes in Ionic Liquid [bmim]PF6: A Facile Method for the Synthesis of Substituted Hydrazinocyclopentene Derivatives

Palladium-Catalyzed Reaction of Bicyclic Hydrazines with Allyl- and Arylstannanes in Ionic Liquid [bmim]PF6: A Facile Method for the Synthesis of Substituted Hydrazinocyclopentene Derivatives

Abstract A method for the synthesis of substituted hydrazinocyclopentenes by the palladium-catalyzed reaction of azabicyclic and tricyclic olefins with organostannanes is described. The reaction is facile with catalytic amount of Lewis acid and the rate of the reaction is enhanced by the use of ioni...

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Veröffentlicht in:Synlett 2005-09, Vol.2005 (15), p.2273-2276
Hauptverfasser: Radhakrishnan, K. V., Sajisha, V. S., Anas, S., Krishnan, K. Syam
Format: Artikel
Sprache:eng
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Zusammenfassung:Abstract A method for the synthesis of substituted hydrazinocyclopentenes by the palladium-catalyzed reaction of azabicyclic and tricyclic olefins with organostannanes is described. The reaction is facile with catalytic amount of Lewis acid and the rate of the reaction is enhanced by the use of ionic liquid, [bmim]PF 6 as solvent.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-2005-872252