Novel Medium Ring Sized Estradiol Derivatives by Intramolecular Heck Reactions

Novel Medium Ring Sized Estradiol Derivatives by Intramolecular Heck Reactions

Abstract New steroids with a seven-, eight- or nine-membered D-ring have been synthesized from a D-SECO-estrone derivative by a Grignard and an intramolecular Heck reaction.

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Veröffentlicht in:Synlett 2003-08, Vol.2003 (10)
Hauptverfasser: Tietze, Lutz F., Sommer, Konrad M., Schneider, Gyula, Tapolcsányi, Pál, Wölfling, János, Müller, Peter, Noltemeyer, Mathias, Terlau, Heinrich
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Sprache:eng
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Zusammenfassung:Abstract New steroids with a seven-, eight- or nine-membered D-ring have been synthesized from a D-SECO-estrone derivative by a Grignard and an intramolecular Heck reaction.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-2003-40832