A Facile and Selective Synthetic Method for the Preparation of Aromatic Dialdehydes from Diesters via the Amine-Modified SMEAH Reduction System
ABSTRACT A new reduction system employing N-methylpiperazine-modified sodium bis(2-methoxyethoxy)aluminum hydride (NMP-SMEAH) for the conversion of aromatic diesters to dialdehydes is described. The method is plain and efficient, and can be carried out under mild and operationally simple conditions...
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| Veröffentlicht in: | Synthesis (Stuttgart) 2003-05, Vol.2003 (6) |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | ABSTRACT
A new reduction system employing N-methylpiperazine-modified
sodium bis(2-methoxyethoxy)aluminum hydride (NMP-SMEAH) for the
conversion of aromatic diesters to dialdehydes is described. The
method is plain and efficient, and can be carried out under mild
and operationally simple conditions applicable for large scale productions. |
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| ISSN: | 0039-7881 1437-210X |
| DOI: | 10.1055/s-2003-38677 |