Unsaturated Sultones from Unsaturated Sulfonates: Synthesis by Ring-Closing Metathesis and Reactivity
Abstract Unsaturated sultones can be efficiently synthesized by ring-closing metathesis of the corresponding unsaturated sulfonates derived from primary and secondary alkenols or alkynols. These compounds can be converted to 1,3-dienes under basic conditions in the presence of carbenoid species.
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| Veröffentlicht in: | Synlett 2003-04, Vol.2003 (5) |
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| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Abstract
Unsaturated sultones can be efficiently synthesized by ring-closing
metathesis of the corresponding unsaturated sulfonates derived from
primary and secondary alkenols or alkynols. These compounds can
be converted to 1,3-dienes under basic conditions in the presence
of carbenoid species. |
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| ISSN: | 0936-5214 1437-2096 |
| DOI: | 10.1055/s-2003-38363 |