Alkylation and acylation of basic salts of anthranilic acid
Basic salts of anthranilic acid were found to exhibit O-nucleophilicity toward alkylating and acylating reagents. The O-nucleophilicity of basic anthranilic acid salts was documented, analyzed, and utilized in synthesis. Specifically substitutions leading to esters instead of secondary amines, and f...
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| Veröffentlicht in: | Tetrahedron letters 2004, Vol.45 (5), p.969-972 |
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| creator | Wiklund, Per Bergman, Jan |
| description | Basic salts of anthranilic acid were found to exhibit O-nucleophilicity toward alkylating and acylating reagents.
The O-nucleophilicity of basic anthranilic acid salts was documented, analyzed, and utilized in synthesis. Specifically substitutions leading to esters instead of secondary amines, and formation of anthranilic acid anhydrides were studied. |
| doi_str_mv | 10.1016/j.tetlet.2003.11.111 |
| format | Article |
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The O-nucleophilicity of basic anthranilic acid salts was documented, analyzed, and utilized in synthesis. Specifically substitutions leading to esters instead of secondary amines, and formation of anthranilic acid anhydrides were studied.</description><subject>Acylation</subject><subject>Alkylation</subject><subject>Anthranilic acid</subject><subject>Medicin och hälsovetenskap</subject><issn>0040-4039</issn><issn>1359-8562</issn><issn>1873-3581</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNp9kU1LAzEQhoMoWKv_wMPeZetMk93NIgilfkLBi3oN-bRp192SrEr_vSm1eqphIJnheYfMvIScI4wQsLxcjHrbN7YfjQHoCDEFHpAB8ormtOB4SAYADHIGtD4mJzEuIJ2Sw4BcTZrlupG979pMtiaTepd1LlMyep1F2fRxk8q2nwfZ-iYVpfbmlBw52UR79nMPycvd7fP0IZ893T9OJ7Ncs3rc5xpcaRSroHCF4bVztmJjrShjTlUFs44qhopr7pxLvzQKDbfAEwwaVIV0SPJt3_hlVx9KrIJ_l2EtOunFT2mZXlaUiBRo4qu9_Cp05k-0E2LNeMF5Ul7sVd7414nowpuIc4EFq6tEsy2tQxdjsO6XRxAbY8RCbI0RG2MEYorNONdbmU07-_Q2iKi9bbU1PljdC9P5_xt8A98cm2Q</recordid><startdate>2004</startdate><enddate>2004</enddate><creator>Wiklund, Per</creator><creator>Bergman, Jan</creator><general>Elsevier Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ADTPV</scope><scope>AOWAS</scope><scope>DF8</scope></search><sort><creationdate>2004</creationdate><title>Alkylation and acylation of basic salts of anthranilic acid</title><author>Wiklund, Per ; Bergman, Jan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c492t-c0f6db4705f5d89ffe742cb344fb754ef3b41b8c8fff040db1d8e08f5d0c0b713</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Acylation</topic><topic>Alkylation</topic><topic>Anthranilic acid</topic><topic>Medicin och hälsovetenskap</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wiklund, Per</creatorcontrib><creatorcontrib>Bergman, Jan</creatorcontrib><collection>CrossRef</collection><collection>SwePub</collection><collection>SwePub Articles</collection><collection>SWEPUB Södertörns högskola- SwePub</collection><jtitle>Tetrahedron letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wiklund, Per</au><au>Bergman, Jan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Alkylation and acylation of basic salts of anthranilic acid</atitle><jtitle>Tetrahedron letters</jtitle><date>2004</date><risdate>2004</risdate><volume>45</volume><issue>5</issue><spage>969</spage><epage>972</epage><pages>969-972</pages><issn>0040-4039</issn><issn>1359-8562</issn><eissn>1873-3581</eissn><abstract>Basic salts of anthranilic acid were found to exhibit O-nucleophilicity toward alkylating and acylating reagents.
The O-nucleophilicity of basic anthranilic acid salts was documented, analyzed, and utilized in synthesis. Specifically substitutions leading to esters instead of secondary amines, and formation of anthranilic acid anhydrides were studied.</abstract><pub>Elsevier Ltd</pub><doi>10.1016/j.tetlet.2003.11.111</doi><tpages>4</tpages></addata></record> |
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| ispartof | Tetrahedron letters, 2004, Vol.45 (5), p.969-972 |
| issn | 0040-4039 1359-8562 1873-3581 |
| language | eng |
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| source | Access via ScienceDirect (Elsevier) |
| subjects | Acylation Alkylation Anthranilic acid Medicin och hälsovetenskap |
| title | Alkylation and acylation of basic salts of anthranilic acid |
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