Water quality in a large complex catchment: Significant effects of land use and soil type but limited ability to detect trends

Globally, significant societal resources are devoted to mitigating negative effects of eutrophication from excessive phosphorus (P) and nitrogen (N) loading. Potential effectiveness of mitigation measures and possible confounding factors are often assessed using studies conducted in headwater catchments. However, success is often evaluated based on trends in river mouth water chemistry. It is not clear how transferrable insights from headwater catchments are to larger rivers. Here, relationships between P and suspended solids (SS) identified in small agricultural headwater catchments were applied to 30 larger, mixed land use catchments draining into Mälaren, a Swedish great lake. Relationships identified in headwater streams between SS concentration, catchment agricultural land percentage and arable land clay content were corroborated for the larger catchments (R2 = 0.59, p-value