The frequency factor in statistical fullerene decay

The frequency factor in statistical fullerene decay

Experiments on fullerene decay are reviewed and the frequency factor for C 2 emission is extracted. The value is also calculated theoretically. Inclusion of a number of previously disregarded degrees of freedom for the products increase the theoretical estimate for C 60 to above 10 20 s −1, in good...

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Veröffentlicht in:International journal of mass spectrometry 2006-05, Vol.252 (2), p.79-95
Hauptverfasser: Hansen, K., Campbell, E.E.B., Echt, O.
Format: Artikel
Sprache:eng
Schlagworte:
Atom and Molecular Physics and Optics
Atom- och molekylfysik och optik
Fullerene
Fysik
Physical Sciences
Unimolecular decay
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Beschreibung
Zusammenfassung:Experiments on fullerene decay are reviewed and the frequency factor for C 2 emission is extracted. The value is also calculated theoretically. Inclusion of a number of previously disregarded degrees of freedom for the products increase the theoretical estimate for C 60 to above 10 20 s −1, in good agreement with experimental results.
ISSN:1387-3806
1873-2798
DOI:10.1016/j.ijms.2006.01.052