Angular anisotropy in resonant inelastic soft X-ray scattering of liquid water

Resonantly excited soft x-ray emission spectra of liquid water have been measured at two different angles relative to the polarization direction of the exciting radiation. The results demonstrate that the emission is much more isotropic than expected for the free water   molecule but that the trends...

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Veröffentlicht in:Physical review. B, Condensed matter and materials physics Condensed matter and materials physics, 2009, Vol.79 (13), p.132203
Hauptverfasser: Forsberg, Johan, Gråsjö, Johan, Brena, Barbara, Nordgren, Joseph, Duda, Laurent, Rubensson, Jan-Erik
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Sprache:eng
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Zusammenfassung:Resonantly excited soft x-ray emission spectra of liquid water have been measured at two different angles relative to the polarization direction of the exciting radiation. The results demonstrate that the emission is much more isotropic than expected for the free water   molecule but that the trends in the remaining anisotropy qualitatively agree. It is found that the two sharp oxygen peaks at high emission energy correspond to states of different symmetry.  
ISSN:1098-0121
1550-235X
DOI:10.1103/PhysRevB.79.132203