Determination of absolute configuration of (pi-allyl)palladium complexes by NMR spectroscopy and stereoselective complexation

Determination of absolute configuration of (pi-allyl)palladium complexes by NMR spectroscopy and stereoselective complexation

The chiral chelating ligand N,N'-bis(phenylethyl)bispidine (1) forms a rigid cavity which accommodates (rc-allyl)palladium species with high selectivity In the resulting complex, the absolute configuration of the re-allyl ligand can be determined by the d

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Veröffentlicht in:Chemistry : a European journal 2001, Vol.7 (2), p.396
Hauptverfasser: Gogoll, Adolf, Johansson, Charlotte, Axen, Andreas, Grennberg, Helena
Format: Artikel
Sprache:eng
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Zusammenfassung:The chiral chelating ligand N,N'-bis(phenylethyl)bispidine (1) forms a rigid cavity which accommodates (rc-allyl)palladium species with high selectivity In the resulting complex, the absolute configuration of the re-allyl ligand can be determined by the d
ISSN:0947-6539
DOI:10.1002/1521-3765(20010119)