Voltammetric and spectroscopic characterization of early intermediates in the Co(II)-polypyridyl-catalyzed reduction of water

Early intermediates of catalytic water reduction by a Co(II)-polypyridyl species have been characterized. Electrochemical detection of the Co(III)-hydride and time-resolved spectroscopic detection of the Co(I)-ligand intermediates provide an understanding of their reactivity in electrolytic or light...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2013-01, Vol.49 (77), p.8638-8640
Hauptverfasser:	Singh, Wangkheimayum Marjit, Mirmohades, Mohammad, Jane, Reuben T, White, Travis A, Hammarström, Leif, Thapper, Anders, Lomoth, Reiner, Ott, Sascha
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Early intermediates of catalytic water reduction by a Co(II)-polypyridyl species have been characterized. Electrochemical detection of the Co(III)-hydride and time-resolved spectroscopic detection of the Co(I)-ligand intermediates provide an understanding of their reactivity in electrolytic or light-driven reduction of protons to hydrogen.
ISSN:	1359-7345 1364-548X 1364-548X
DOI:	10.1039/c3cc44655g