Bicyclic phosphine-thiazole ligands for the asymmetric hydrogenation of olefins

Bicyclic phosphine-thiazole ligands for the asymmetric hydrogenation of olefins

New bicyclic thiazole-based chiral N,P-chelating ligands were developed. High activities and enantioselectivities were achieved in the iridium-catalyzed asymmetric hydrogenation of olefins with the new ligands.

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Veröffentlicht in:Tetrahedron: asymmetry 2010-06, Vol.21 (11), p.1328-1333
Hauptverfasser: Li, Jia-Qi, Paptchikhine, Alexander, Govender, Thavendran, Andersson, Pher G.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Kemi
NATURAL SCIENCES
NATURVETENSKAP
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Beschreibung
Zusammenfassung:New bicyclic thiazole-based chiral N,P-chelating ligands were developed. High activities and enantioselectivities were achieved in the iridium-catalyzed asymmetric hydrogenation of olefins with the new ligands.
ISSN:0957-4166
1362-511X
1362-511X
DOI:10.1016/j.tetasy.2010.03.023