A Kinetic Study of the Liquid Phase Acetoxylation of α-Pinene

A Kinetic Study of the Liquid Phase Acetoxylation of α-Pinene

The present study introduces kinetic modeling of liquid phase α-pinene acetoxylation with acetic acid over an ion-exchange resin catalyst. The reaction was carried out in a laboratory scale high-pressure autoclave. α-terpinyl (35 wt%) and bornyl (40 wt%) acetates were the primary products. The predo...

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Veröffentlicht in:Topics in catalysis 2012-07, Vol.55 (7-10), p.649-656
Hauptverfasser: Golets, M., Ajaikumar, S., Larsson, W., Blomberg, D., Grundberg, H., Wärnå, J., Salmi, T., Mikkola, J.-P.
Format: Artikel
Sprache:eng
Schlagworte:
Acetoxylation
Amberlyst 70
Batch process
Biorefinery
Catalysis
Characterization and Evaluation of Materials
Chemistry
Chemistry and Materials Science
Industrial Chemistry/Chemical Engineering
Kinetic modeling
Liquid phase
Original Paper
Pharmacy
Physical Chemistry
α-pinene
α-terpinyl acetate
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Beschreibung
Zusammenfassung:The present study introduces kinetic modeling of liquid phase α-pinene acetoxylation with acetic acid over an ion-exchange resin catalyst. The reaction was carried out in a laboratory scale high-pressure autoclave. α-terpinyl (35 wt%) and bornyl (40 wt%) acetates were the primary products. The predominant reaction pathways were identified and evaluated.
ISSN:1022-5528
1572-9028
1572-9028
DOI:10.1007/s11244-012-9844-9