The Pressure Dependence of Oxygen Isotope Exchange Rates Between Solution and Apical Oxygen Atoms on the [UO2(OH)4]2− Ion

Under pressure: The pressure dependence of isotope exchange rate was determined for apical oxygen atoms in the [UO2(OH)4]2−(aq) ion (see picture). The results can be interpreted to indicate an associative character of the reaction.

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Angewandte Chemie (International ed.) 2011-05, Vol.50 (19), p.4467-4469
Hauptverfasser:	Harley, Steven J., Ohlin, C. André, Johnson, Rene L., Panasci, Adele F., Casey, William H.
Format:	Artikel
Sprache:	eng
Schlagworte:	activation volume INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY NMR spectroscopy nuclear (including radiation effects), materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly) oxygen atom exchange reaction kinetics uranium
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	Under pressure: The pressure dependence of isotope exchange rate was determined for apical oxygen atoms in the [UO2(OH)4]2−(aq) ion (see picture). The results can be interpreted to indicate an associative character of the reaction.
ISSN:	1433-7851 1521-3773 1521-3773
DOI:	10.1002/anie.201006961