An ice phase of lowest thermal conductivity
On pressurizing at temperatures near 130 K, hexagonal and cubic ices transform implosively at 0.8-1 GPa. The phase produced on transformation has the lowest thermal conductivity among the known crystalline ices and its value decreases on increase in temperature. An ice phase of similar thermal condu...
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Veröffentlicht in: | The Journal of chemical physics 2004-05, Vol.120 (20), p.9612-9617 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | On pressurizing at temperatures near 130 K, hexagonal and cubic ices transform implosively at 0.8-1 GPa. The phase produced on transformation has the lowest thermal conductivity among the known crystalline ices and its value decreases on increase in temperature. An ice phase of similar thermal conductivity is produced also when high-density amorphous ice kept at 1 GPa transforms on slow heating when the temperature reaches approximately 155 K. These unusual formation conditions, the density and its distinguished thermal conductivity, all indicate that a distinct crystal phase of ice has been produced. |
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ISSN: | 0021-9606 1089-7690 1089-7690 |
DOI: | 10.1063/1.1703523 |