Collision-induced dissociation of ∼ 2-MeV O 3 + and N 3 + ions

We present a study into the collision-induced dissociation (possibly including electron stripping) of O-3(+) and N-3(+) with rest gas molecules (predominantly H-2) in the heavy-ion storage ring CRYRING. The projectile ions had kinetic energies of 1.96 MeV (O-3(+)) and 2.25 MeV (N-3(+)) and from the...

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Veröffentlicht in:Physical review. A, Atomic, molecular, and optical physics Atomic, molecular, and optical physics, 2013-05, Vol.87 (5), Article 052707
Hauptverfasser: Vigren, E., Zhaunerchyk, V., Geppert, W. D., Larsson, M., Bahati, E., Vane, C. R., Bannister, M. E., Fogle, M. R., Hamberg, M., Danielsson, M., Kaminska, M., Thomas, R. D.
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Sprache:eng
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Zusammenfassung:We present a study into the collision-induced dissociation (possibly including electron stripping) of O-3(+) and N-3(+) with rest gas molecules (predominantly H-2) in the heavy-ion storage ring CRYRING. The projectile ions had kinetic energies of 1.96 MeV (O-3(+)) and 2.25 MeV (N-3(+)) and from the experimental data we could derive the relative importance of the channels that produce at least one neutral product fragment. The dominant type of fragmentation for both ions involves the production of a single neutral fragment, namely an individual atom. We also find pronounced dissimilarities when comparing the O-3(+) and N-3(+) results, which we link to the stronger chemical bonds in the nitrogen system.
ISSN:1050-2947
1094-1622
1094-1622
DOI:10.1103/PhysRevA.87.052707