Palladium-Catalyzed Electrophilic Substitution via Monoallylpalladium Intermediates

Palladium-Catalyzed Electrophilic Substitution via Monoallylpalladium Intermediates

Nucleophilic rather than electrophilic reactivity is ascribed to the allyl moiety in (η1‐allyl)palladium complexes such as 1, which are generated catalytically from allylstannanes and a palladium pincer complex and react smoothly with aldehydes.

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Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie International Edition 2003-08, Vol.42 (31), p.3656-3658
Hauptverfasser: Solin, Niclas, Kjellgren, Johan, Szabó, Kálmán J.
Format: Artikel
Sprache:eng
Schlagworte:
aldehydes
allylation
electrophilic substitution
homogenous catalysis
palladium
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Beschreibung
Zusammenfassung:Nucleophilic rather than electrophilic reactivity is ascribed to the allyl moiety in (η1‐allyl)palladium complexes such as 1, which are generated catalytically from allylstannanes and a palladium pincer complex and react smoothly with aldehydes.
ISSN:1433-7851
1521-3773
1521-3773
DOI:10.1002/anie.200351477