One-step microwave-assisted synthesis of amino-functionalized chromium(III) terephthalate MIL-101-NH2

One-step microwave-assisted synthesis of amino-functionalized chromium(III) terephthalate MIL-101-NH2

A single-step microwave (MW)-assisted protocol for the synthesis of MIL-101(Cr) and of MIL-101(Cr)-NH2 is described herein, based on the addition of NaF as the modulator instead of hydrofluoric acid to obtain the corresponding polymers in only 1 h with high crystallinity and yields (>70%, 0.5 g)....

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Veröffentlicht in:Materials today chemistry 2023-07, Vol.31, p.101618, Article 101618
Hauptverfasser: Carretero-Cerdán, A., Carrasco, S., Sanz-Marco, A., Jaworski, A., Martín-Matute, B.
Format: Artikel
Sprache:eng
Schlagworte:
Ecofriendly
Ef ficient
Efficient
Microwave-assisted protocol
MIL-101(Cr)-NH 2
MIL-101(Cr)-NH2
One step
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Zusammenfassung:A single-step microwave (MW)-assisted protocol for the synthesis of MIL-101(Cr) and of MIL-101(Cr)-NH2 is described herein, based on the addition of NaF as the modulator instead of hydrofluoric acid to obtain the corresponding polymers in only 1 h with high crystallinity and yields (>70%, 0.5 g). Compared to classic solvothermal protocols (12–72 h,
ISSN:2468-5194
2468-5194
DOI:10.1016/j.mtchem.2023.101618