One-pot synthesis of tripodal tris(2-aminoethyl)amine derivatives from seven molecular components
Complex tripodal tris(2-aminoethyl)amine (tren)-based ligands have been prepared in a single-pot reaction of tren with 3 equiv each of cyclohexenone and a benzaldehyde derivative (i.e., from seven components and three molecular types). The highest yield of product was obtained for p-nitrobenzaldehyd...
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Veröffentlicht in: | Tetrahedron letters 2009-04, Vol.50 (16), p.1847-1850 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Complex tripodal tris(2-aminoethyl)amine (tren)-based ligands have been prepared in a single-pot reaction of tren with 3
equiv each of cyclohexenone and a benzaldehyde derivative (i.e., from seven components and three molecular types). The highest yield of product was obtained for
p-nitrobenzaldehyde, the most electrophilic aldehyde used. |
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ISSN: | 0040-4039 1359-8562 1873-3581 |
DOI: | 10.1016/j.tetlet.2009.02.008 |