Dissolved beryllium (< 1 kDa) mobilized as a major element in groundwater in legacy mine waste

Research regarding the geochemistry of beryllium (Be) in terrestrial environments is hindered by its high toxicity to humans and the low concentrations normally occurring in the environment. Although Be is considered an immobile element, extremely high dissolved concentrations have been detected in groundwater in the legacy Tailings Storage Facility (TSF) of Smaltjärnen, Sweden. Therefore, a detailed study was conducted to determine physiochemical parameters affecting the speciation of Be in the groundwater. Groundwater was sampled from 2016 to 2024 and filtered through 0.2 μm filters, whereas truly dissolved fraction (0.2 μm) together with F and Zn. Secondary minerals on the shore of the tailings functioned as a temporary chemical barrier, scavenging Be primarily by secondary gypsum when present and otherwise by Fe-(hydr)oxides. [Display omitted] •Dissolved Be (average: 4.8 mg/L) mobilized in suboxic groundwater with pH 6.0–6.4•>90% of the Be (