A nano to macroscale study on structure-mechanics relationships of archaeological oak

Mechanical properties of wood at different length scales of its hierarchical structure are governed by structural and compositional properties on smaller length scales. This opens up the possibility to use microstructural data for estimating mechanical properties, which are difficult to assess by conventional, destructive testing but are nevertheless of high relevance for conservation practice. Herein, we investigate such microstructure-mechanics relationships for a particular example, namely the load bearing archaeological oak of the Oseberg Viking ship, displayed at the Viking Ship Museum in Oslo, Norway. In order to identify the effects of degradation on the mechanical behavior and their relations to the microstructure, recent oak specimens of different geographical origin (Norway and Austria) are investigated as well. Wood exhibits a cellular structure. Its cell walls are composed of an amorphous polymer matrix consisting of lignin and hemicelluloses and embedded, stiff cellulose fibers. At the cell level, experimental studies comprised microscopic investigations of the cellular structure, chemical analyses of the composition of the cell walls, as well as nanoindentation tests on single cell walls. The same samples were also analyzed on the macroscopic level, where additionally mass density and annual ring data were measured together with ultrasonic stiffnesses. The chemical data clearly indicate deterioration in the archaeological oak, affecting mainly hemicelluloses and amorphous cellulose. At the cell wall scale, however, this does not necessarily lead to a weaker material behavior. The nanoindentation modulus, as a measure of the cell wall stiffness, was found to even increase. This is counterintuitive to our understanding of the effects of chemical degradation. It might be due to possible modification of lignin in the Oseberg oak, and thus have a stronger effect on the indentation modulus than the concurrent weakening of the interfaces between the load-carrying cellulose fibers and the connecting cell wall matrix when analyzing wood at the microscopic level. A similar effect is also observed for the transversal stiffness of macroscopic samples, which increases. In tension-dominated loading modes, however, the degradation of the interfaces is the dominant effect, resulting for example in a considerable reduction of the macroscopic stiffness in longitudinal direction. This underlines the utmost relevance of the loading condition on the remaining loa