(4S,5S)-2,2,4-Triethyl-5-methyl-1,3-dioxolane: A New Volatile Released by a Triatomine Bug

(4S,5S)-2,2,4-Triethyl-5-methyl-1,3-dioxolane: A New Volatile Released by a Triatomine Bug

Adults of the triatomine bug Triatoma brasiliensis release 2,2,4-triethyl-5-methyl-1,3-dioxolane (1) as a mixture of the (4S,5S)- and (4R,5R)-enantiomers in a ratio of 4:1. Among the volatile acetals identified from insects so far, this is the first example resulting from an intermolecular condensat...

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Veröffentlicht in:Organic letters 2010-12, Vol.12 (24), p.5601-5603
Hauptverfasser: Unelius, C. R, Bohman, B, Lorenzo, M. G, Tröger, A, Franke, S, Francke, W
Format: Artikel
Sprache:eng
Schlagworte:
Animals
chemical ecology
Chemistry
dioxolanes
Dioxolanes - chemistry
Ecological chemistry
Ekologisk kemi
Kemi
Molecular Structure
NATURAL SCIENCES
NATURVETENSKAP
Organic chemistry
Organic synthesis
Organisk kemi
Organisk syntes
semiochemicals
Triatominae - chemistry
Triatomines
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Beschreibung
Zusammenfassung:Adults of the triatomine bug Triatoma brasiliensis release 2,2,4-triethyl-5-methyl-1,3-dioxolane (1) as a mixture of the (4S,5S)- and (4R,5R)-enantiomers in a ratio of 4:1. Among the volatile acetals identified from insects so far, this is the first example resulting from an intermolecular condensation of a carbonyl moiety and a diol substructure.
ISSN:1523-7060
1523-7052
1523-7052
DOI:10.1021/ol102165q