Covalent coupling via dehalogenation on Ni(111) supported boron nitride and graphene

Covalent coupling via dehalogenation on Ni(111) supported boron nitride and graphene

Polymerization of 1,3,5-tris(4-bromophenyl)benzene via dehalogenation on graphene and hexagonal boron nitride is investigated by scanning tunneling microscopy experiments and density functional theory calculations. This work reveals how the interactions between molecules and graphene or h-BN grown o...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2015-01, Vol.51 (12), p.2440-2443
Hauptverfasser: Morchutt, Claudius, Björk, Jonas, Krotzky, Sören, Gutzler, Rico, Kern, Klaus
Format: Artikel
Sprache:eng
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Zusammenfassung:Polymerization of 1,3,5-tris(4-bromophenyl)benzene via dehalogenation on graphene and hexagonal boron nitride is investigated by scanning tunneling microscopy experiments and density functional theory calculations. This work reveals how the interactions between molecules and graphene or h-BN grown on Ni(111) govern the surface-confined synthesis of polymers through C-C coupling.
ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/c4cc07107g