Highly Efficient Oxidation of Water by a Molecular Catalyst Immobilized on Carbon Nanotubes

A successful team: A molecular device based on multiwalled carbon nanotubes functionalized by a mononuclear ruthenium catalyst has been shown to split water electrochemically (see picture; ITO=indium tin oxide). The readily prepared electrode showed excellent electrocatalytic activity for the oxidat...

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Veröffentlicht in:Angewandte Chemie International Edition 2011-12, Vol.50 (51), p.12276-12279
Hauptverfasser: Li, Fei, Zhang, Biaobiao, Li, Xiaona, Jiang, Yi, Chen, Lin, Li, Yanqing, Sun, Licheng
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Sprache:eng
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Zusammenfassung:A successful team: A molecular device based on multiwalled carbon nanotubes functionalized by a mononuclear ruthenium catalyst has been shown to split water electrochemically (see picture; ITO=indium tin oxide). The readily prepared electrode showed excellent electrocatalytic activity for the oxidation of water, a high current density, and a low overpotential, and constitutes one step forward in the design of artificial photosynthetic systems.
ISSN:1433-7851
1521-3773
1521-3773
DOI:10.1002/anie.201105044