Inference of Retention Time From Tracer Tests in Crystalline Rock

A statistical parametrization of transport combined with a new, general partition function for diffusive mass transfer (Cvetkovic, 2017, https://doi.org/10.1002/2017WR021187) is here developed into a practical tool for evaluating tracer tests in crystalline rock. The research question of this study is how to separate the characteristic times of retention and advection, using tracer test information alone; this decoupling is critical for upscaling of transport. Three regimes are identified based on the unconditional mean number of trapping events. Analytical expressions are derived for inferring transport‐retention parameters; these are first tested on a series of generic examples and then using two sets of tracer test data. Our results indicate that the key transport‐retention parameters can be inferred separately with reasonable accuracy by a few simple steps, provided that the macrodispersion is not too large and retention not too strong. Of particular interest is inference of the retention time from the breakthrough curve peak that avoids costly asymptotic monitoring. Finally, we summarize the retention times as inferred from a series of nonsorbing tracer tests in the Swedish granite, demonstrating the uncertainties when estimating retention based on material and structural properties from samples. Possible strategies for reducing these uncertainties that combine improved understanding of crystalline rock evolution with numerical simulations are noted as topics for future research. Key Points Tracer tests are the only in situ evidence of retention in granite and hence are important, for example, in the context of geological waste disposal Novel methodology is developed and implemented for separating effects of retention and hydrodynamic transport critical for upscaling Relating key transport‐retention parameters to independent information on material and structural properties of rocks is highly uncertain