New representative of Bi-9(5+)-containing phases: synthesis and crystal structure of the Nb-IV-containing Bi10Nb3Cl18 compound

New representative of Bi-9(5+)-containing phases: synthesis and crystal structure of the Nb-IV-containing Bi10Nb3Cl18 compound

The Bi10Nb3Cl18 compound was prepared using the high-temperature ampoule method, and its crystal structure was determined by sing-le-crystal X-ray diffraction. This phase contains the Bi-9(5+) cluster polycations and Bi+ cations surrounded by the NbCl62- complex anions. The latter contain the parama...

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Veröffentlicht in:Russian chemical bulletin 2003-10, Vol.52 (10), p.2100
Hauptverfasser: Kuznetsov, A. N., Naumenko, P. I., Popovkin, B. A., Kloo, Lars A.
Format: Artikel
Sprache:eng
Schlagworte:
bismuth polycations
cluster
clusters
subhalides
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Zusammenfassung:The Bi10Nb3Cl18 compound was prepared using the high-temperature ampoule method, and its crystal structure was determined by sing-le-crystal X-ray diffraction. This phase contains the Bi-9(5+) cluster polycations and Bi+ cations surrounded by the NbCl62- complex anions. The latter contain the paramagnetic central Nb-IV ions, as evidenced by magnetic measurements.
ISSN:1573-9171
1066-5285
DOI:10.1023/B:RUCB.0000011864.81356.cc