Towards single-molecule in situ electrochemical SERS detection with disposable substrates

Dynamic time-resolved Raman spectroelectrochemistry demonstrates the strong influence of nanostructuring and surface charge of in situ activated disposable substrates for SERS detection. Under specific conditions, a large enhancement factor and estimated calculations agree with the feasible detectio...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2018, Vol.54 (45), p.5748-5751
Hauptverfasser: Martín-Yerga, Daniel, Pérez-Junquera, Alejandro, González-García, María Begoña, Hernández-Santos, David, Fanjul-Bolado, Pablo
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Sprache:eng
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Zusammenfassung:Dynamic time-resolved Raman spectroelectrochemistry demonstrates the strong influence of nanostructuring and surface charge of in situ activated disposable substrates for SERS detection. Under specific conditions, a large enhancement factor and estimated calculations agree with the feasible detection of only a few molecules, approaching the limit of single-entity detection.
ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/c8cc02069h