A swivel-cruciform thiophene based hole-transporting material for efficient perovskite solar cells

A novel swivel-cruciform 3,3'-bithiophene based hole-transporting material (HTM) with a low lying highest occupied molecular orbital (HOMO) level was synthesized. This new HTM (KTM3) in CH sub(3)NH sub(3)PbI sub(3 ) perovskite solar cells showed a higher V sub(oc) (1.08 V) and fill factor (78.3...

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Veröffentlicht in:Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2014-01, Vol.2 (18), p.6305-6309
Hauptverfasser: Krishnamoorthy, Thirumal, Kunwu, Fu, Boix, Pablo P, Li, Hairong, Koh, Teck Ming, Leong, Wei Lin, Powar, Satvasheel, Grimsdale, Andrew, Graetzel, Michael, Mathews, Nripan, Mhaisalkar, Subodh G
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Sprache:eng
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Zusammenfassung:A novel swivel-cruciform 3,3'-bithiophene based hole-transporting material (HTM) with a low lying highest occupied molecular orbital (HOMO) level was synthesized. This new HTM (KTM3) in CH sub(3)NH sub(3)PbI sub(3 ) perovskite solar cells showed a higher V sub(oc) (1.08 V) and fill factor (78.3%) compared to solar cells fabricated using the widely used spiro-OMeTAD.
ISSN:2050-7488
2050-7496
2050-7496
DOI:10.1039/c4ta00486h