Network Formation of Interlocked Copolymer Obtained from Copolymerization of 1,2-Dithiane and Lipoic Acid by Metal Salt: Review Article

Network formation of interlocked copolymer obtained from the thermal ring-opening copolymerization of 1,2-dithiane (DT) and liopic acid (LPA) was investigated by the reaction of the poly(LPA- co -DT) and Zn(acetate) 2 . From the IR spectra of the reaction products, the reaction was induced readily t...

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Veröffentlicht in:Polymer journal 2007-12, Vol.39 (12), p.1360-1364
Hauptverfasser: Yamanaka, Taku, Endo, Kiyoshi
Format: Artikel
Sprache:eng
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Zusammenfassung:Network formation of interlocked copolymer obtained from the thermal ring-opening copolymerization of 1,2-dithiane (DT) and liopic acid (LPA) was investigated by the reaction of the poly(LPA- co -DT) and Zn(acetate) 2 . From the IR spectra of the reaction products, the reaction was induced readily to make a enough high degree of cross-linking in which the cross-linking points are polycatenane using a bifunctional metal salts by effective an ionomeric network. The cross-linking reaction of the precursor copolymer gave more thermo-stable product by the formation of the enough high degree of cross-linking structure.
ISSN:0032-3896
1349-0540
DOI:10.1295/polymj.PJ2007069