Side-Chain Effects on Friction-Transferred Polymer Orientation: Review Article

Effects of substituted side-chains of poly(2,5-dialkoxy-1,4-phenylenevinylene) derivatives (PPV) on polymer orientation have been studied using polarized optical spectroscopy and synchrotron-sourced grazing incidence X-ray diffraction (GIXD) analysis. The results of polarized optical spectroscopy in...

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Veröffentlicht in:Polymer journal 2007-12, Vol.39 (12), p.1300-1305
Hauptverfasser: Nagamatsu, Shuichi, Misaki, Masahiro, Kimura, Tatsumi, Yoshida, Yuji, Azumi, Reiko, Tanigaki, Nobutaka, Yase, Kiyoshi
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Sprache:eng
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Zusammenfassung:Effects of substituted side-chains of poly(2,5-dialkoxy-1,4-phenylenevinylene) derivatives (PPV) on polymer orientation have been studied using polarized optical spectroscopy and synchrotron-sourced grazing incidence X-ray diffraction (GIXD) analysis. The results of polarized optical spectroscopy indicate that the symmetrically substituted PPV is suitable for homogeneous oriented film preparation by friction-transfer technique. The formed film of poly(2,5-(2-ethylhexyloxy)-1,4-phenylenevinylene) (BEHPPV) exhibited large light emission dichroism of up to 42.0. The results of synchrotron-sourced GIXD for BEHPPV film indicated that the BEHPPV molecules crystallized in not a different manner from that of other PPV.
ISSN:0032-3896
1349-0540
DOI:10.1295/polymj.PJ2007062