The regular features of chlorine formation in the systems NaCl-MexOy-O2 and Ca(Zn)Cl2-MexOy-O2

The reaction of sodium, calcium, and zinc chlorides with atmospheric oxygen in the presence of transition metal oxides and antimony oxide at temperatures exceeding the melting temperatures of chlorides was studied. The content of chorine, product of oxidation of chloride ions in molten NaCl and CaCl...

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Veröffentlicht in:	Russian journal of applied chemistry 2009, Vol.82 (9), p.1510-1514
Hauptverfasser:	Rozdyalovskaya, T. A., Chekryshkin, Yu. S., Chudinov, A. N., Fedorov, A. A.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Chemistry and Materials Science Chemistry/Food Science Industrial Chemistry/Chemical Engineering Inorganic Synthesis and Industrial Inorganic Chemistry
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	The reaction of sodium, calcium, and zinc chlorides with atmospheric oxygen in the presence of transition metal oxides and antimony oxide at temperatures exceeding the melting temperatures of chlorides was studied. The content of chorine, product of oxidation of chloride ions in molten NaCl and CaCl 2 , was determined as a function of the polarization force of cations of transition metal oxides.
ISSN:	1070-4272 1608-3296
DOI:	10.1134/S107042720909002X