Few-mode metal-free perovskite optical fiber with second-order optical nonlinearity
Semiconductor core optical fibers are highly desirable for fiber-based photonic and optoelectronic applications as they can combine strong optical nonlinearities, tight light confinement, wide transmission bands, and electronic functionality within a single platform. Perovskites have emerged as part...
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Veröffentlicht in: | APL photonics 2024-03, Vol.9 (3), p.036106-036106-9 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Semiconductor core optical fibers are highly desirable for fiber-based photonic and optoelectronic applications as they can combine strong optical nonlinearities, tight light confinement, wide transmission bands, and electronic functionality within a single platform. Perovskites have emerged as particularly exciting materials for semiconductor photonics as they have strong optical nonlinearities and tunable optoelectronic bandgaps. However, lead-based perovskites contain toxic elements and are, therefore, not environmentally friendly. Furthermore, in fiber form, their core-size is prohibitively large, making them unsuitable for nonlinear optics and applications that require single-mode guidance, such as telecommunications. Here, we report a metal-free perovskite core optical fiber where lead has been substituted for an ammonium cation in the perovskite structure. The core material has a wide bandgap greater than 5 eV, a high laser damage threshold, and a core diameter that can be produced as small as 5 µm. At this core size, the fiber supports just six modes, and the fundamental mode can readily be excited and isolated. Moreover, the metal-free perovskite has a second-order susceptibility that is absent in the archetypal lead-based perovskites and many other semiconductor core materials, such as silicon and germanium. The second-order susceptibility is important for many nonlinear optics applications, such as second-harmonic generation and quantum optics. |
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ISSN: | 2378-0967 2378-0967 |
DOI: | 10.1063/5.0186789 |