Steady-state thermodynamics of a system with heat and mass flow coupling

Equilibrium thermodynamics describes the energy exchange of a body with its environment. Here, we describe the global energy exchange of an ideal gas in the Coutte flow in a thermodynamic-like manner. We derive a fundamental relation between internal energy as a function of parameters of state. We a...

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Veröffentlicht in:The Journal of chemical physics 2023-11, Vol.159 (19)
Hauptverfasser: Makuch, Karol, Hołyst, Robert, Giżyński, Konrad, Maciołek, Anna, Żuk, Paweł J.
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Sprache:eng
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Zusammenfassung:Equilibrium thermodynamics describes the energy exchange of a body with its environment. Here, we describe the global energy exchange of an ideal gas in the Coutte flow in a thermodynamic-like manner. We derive a fundamental relation between internal energy as a function of parameters of state. We analyze a non-equilibrium transition in the system and postulate the extremum principle, which determines stable steady states in the system. The steady-state thermodynamic framework resembles equilibrium thermodynamics.
ISSN:0021-9606
1089-7690
DOI:10.1063/5.0170079