Magnetically superior and easy to handle L 1 0 -FePt nanocrystals
We report synthesis of monodisperse L 1 0 -FePt nanocrystals that are not only superior in magnetism but also easy to handle through being dispersible in solvents. Thanks to a thick Si O 2 coating, the thermal treatment needed to form the L 1 0 structure can be done even at 900 ° C without inducing...
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Veröffentlicht in: | Applied physics letters 2005-07, Vol.87 (3), p.032503-032503-3 |
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Zusammenfassung: | We report synthesis of monodisperse
L
1
0
-FePt nanocrystals that are not only superior in magnetism but also easy to handle through being dispersible in solvents. Thanks to a thick
Si
O
2
coating, the thermal treatment needed to form the
L
1
0
structure can be done even at
900
°
C
without inducing coalescence and coarsening. The protecting shell was thereafter removed in a specific way that enabled us to recover the
L
1
0
-FePt nanocrystals in a water dispersion. The
Si
O
2
-coated nanocrystals show a high coercivity of
18.5
kOe
at room temperature in spite of their core size of only
6.5
nm
in diameter, and the hysteresis loop of the water-dispersed nanocrystals, which were frozen under an external field, was almost rectangular indicating that their magnetic and structural orientation could be attained. |
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ISSN: | 0003-6951 1077-3118 |
DOI: | 10.1063/1.1995959 |