Spin-exchange effects in elastic electron scattering from linear triatomic radicals

In this work, we present a theoretical investigation on spin-exchange effects in elastic electron collisions by two linear triatomic free radicals namely, NCN and CNN. Spin-polarization differential and integral cross sections calculated in the (1-10) eV energy range are reported. For both targets,...

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Veröffentlicht in:Journal of the Brazilian Chemical Society 2010, Vol.21 (2), p.226-233
Hauptverfasser: Fujimoto, M. M., Michelin, S. E., Arretche, F., Mazon, K.T., Lee, M.-T., Iga, I.
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Sprache:eng
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Zusammenfassung:In this work, we present a theoretical investigation on spin-exchange effects in elastic electron collisions by two linear triatomic free radicals namely, NCN and CNN. Spin-polarization differential and integral cross sections calculated in the (1-10) eV energy range are reported. For both targets, our study has shown that the exchange between the scattering and the unpaired target electrons is strongly influenced by the occurrence of shape resonances. As a consequence, significant spin-polarization fractions are only observed in the resonance region.
ISSN:0103-5053
1678-4790
DOI:10.1590/S0103-50532010000200006