A concise enantioselective synthesis of (+)-endo-brevicomin accomplished by a tellurium/metal exchange reaction

A concise enantioselective synthesis of (+)-endo-brevicomin accomplished by a tellurium/metal exchange reaction

A homoenolate generated by tellurium/lithium exchange reaction was employed in a straightforward enantioselective synthesis of (+)-endo-brevicomin in 70% yield and 84.4% e.e.

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Veröffentlicht in:Journal of the Brazilian Chemical Society 2008, Vol.19 (5), p.811-812
Hauptverfasser: Ferrarini, Renan S., Princival, Jefferson L., Comasseto, João V., Dos Santos, Alcindo A.
Format: Artikel
Sprache:eng
Schlagworte:
CHEMISTRY, MULTIDISCIPLINARY
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Zusammenfassung:A homoenolate generated by tellurium/lithium exchange reaction was employed in a straightforward enantioselective synthesis of (+)-endo-brevicomin in 70% yield and 84.4% e.e.
ISSN:0103-5053
1678-4790
DOI:10.1590/S0103-50532008000500002