Impact of Cu and Cu species on the oxide-metal transition processes of CuO foams during the CORR probed by Quick-XAS
As a promising electrocatalyst for the CO 2 reduction reaction (CO 2 RR), Cu/Cu oxide (Cu x O) derived materials have been intensively studied in the last few decades. However, it is still poorly understood how the structure of Cu/Cu x O precursors and their simultaneous reduction process influence...
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Veröffentlicht in: | Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2024-10, Vol.12 (41), p.28177-28192 |
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Zusammenfassung: | As a promising electrocatalyst for the CO
2
reduction reaction (CO
2
RR), Cu/Cu oxide (Cu
x
O) derived materials have been intensively studied in the last few decades. However, it is still poorly understood how the structure of Cu/Cu
x
O precursors and their simultaneous reduction process influence CO
2
RR product distribution. Using Quick X-ray absorption near edge structure spectroscopy (Quick-XANES), we aim to understand the potential-dependent reduction processes of Cu
x
O foam precursors with different Cu
0
: Cu
+
: Cu
2+
ratios to pure metallic Cu during the CO
2
RR. Initially, the Cu
x
O foams were prepared by thermal annealing of electrodeposited Cu foams at 100, 200, 300, and 450 °C in air to vary the Cu
0
: Cu
+
: Cu
2+
ratio and especially the crystallinity of CuO. With these different chemical states and structures, the oxide-metal transition kinetics during the cathodic potential increment (Δ
E
= 100 mV), step (Δ
E
>100 mV), and jump (Δ
E
>500 mV) experiments were comprehensively investigated using multivariate curve resolution-alternating least squares (MCR-ALS) analysis of the Quick-XANES data. This allows in
operando
monitoring of the changes in the chemical state of Cu species particularly in relation to the effect of the previously applied potential. In principle, two rate determining steps can be involved in the CuO reduction to Cu
0
via
intermediate Cu
+
formation. First, our results demonstrate that the oxide-metal transition kinetics strongly depend on the initial abundance of Cu
2+
species and precursor structure (ordered
vs.
amorphous) as well as on the type of chronoamperometric experiment. More precisely, compared to amorphous CuO, a high initial population of crystalline CuO species leads to a significant shift of the oxide-metal transition potential towards lower cathodic values, signifying a lower energy barrier to reduction. In addition, our work reveals that the different chronoamperometric experiments strongly influence the electrochemical stability of Cu
+
species within the Cu
x
O foams during CO
2
electrolysis. Smaller potential steps increase the formation of Cu
+
species and lead to a slowdown in the reduction kinetics.
Operando
Quick-XAS is used to study the reduction kinetics of Cu
x
O foams during the CO
2
RR. The oxide-metal transition potential strongly depends on the initial abundance of Cu
2+
species, precursor structure and type of chronoamperometric experiment. |
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ISSN: | 2050-7488 2050-7496 |
DOI: | 10.1039/d4ta02217c |