Facile and ecofriendly green synthesis of CoO/MgOSiO composites towards efficient asymmetric supercapacitor and oxygen evolution reaction applications

The development of low-cost, eco-friendly, and earth-friendly electrode materials for energy storage and conversion applications is a highly desirable but challenging task for strengthening the existing renewable energy systems. As part of this study, orange peel extract was utilized to synthesize a magnesium oxide-silicon dioxide hybrid substrate system (MgO-SiO 2 ) for coating cobalt oxide nanostructures (Co 3 O 4 ) via hydrothermal methods. A variety of MgO-SiO 2 compositions were used to produce Co 3 O 4 nanostructures. The purpose of using MgO-SiO 2 substrates was to increase the porosity of the final hybrid material and enhance its compatibility with the electrode material. This study investigated the morphology, chemical composition, optical properties, and functional group properties. In hybrid materials, the shape structure is inherited from nanoparticles with uniform size distributions that are well compacted. A relative decrease in the optical band was observed for Co 3 O 4 when deposited onto an MgO-SiO 2 substrate. An improvement in the electrochemical properties of Co 3 O 4 /MgO-SiO 2 composites was observed during the measurements of supercapacitors and oxygen evolution reaction (OER) in alkaline solutions. The Co 3 O 4 /MgO-SiO 2 composite prepared on 0.4 g of the MgO-SiO 2 substrate (sample 2) demonstrated excellent specific capacitance, high energy density, and recycling stability for 40 000 galvanic charge-discharge cycles. The assembled asymmetric supercapacitor (ASC) device demonstrated a specific capacitance of 243.94 F g −1 at a current density of 2 A g −1 . Co 3 O 4 /MgO-SiO 2 composites were found to be highly active towards the OER in 1 M KOH aqueous solution with an overpotential of 340 mV at 10 mA cm −2 and a Tafel slope of 88 mV dc −1 . It was found that the stability and durability were highly satisfactory. Based on the use of orange peel extract, a roadmap was developed for the synthesis of porous hybrid substrates for the development of efficient electrode materials for energy storage and conversion. The development of low-cost, eco-friendly, and earth-friendly electrode materials for energy storage and conversion applications is a highly desirable but challenging task for strengthening the existing renewable energy systems.