Photocatalyst-free hydrothiolation of -difluoroalkenes with thiols

A photocatalyst-free hydrothiolation reaction of aromatic gem -difluoroalkenes was developed under the irradiation of blue light in dimethyl carbonate as a green solvent, leading to α,α-difluoroalkylthioethers in good yields. A photocatalyst-free hydrothiolation reaction of aromatic gem -difluoroalk...

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Veröffentlicht in:New journal of chemistry 2024-05, Vol.48 (2), p.9-93
Hauptverfasser: Zuo, Lin, Zhang, Zhiyang, Yuan, Xiao-Ya, Sun, Kai, Yu, Bing
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Zusammenfassung:A photocatalyst-free hydrothiolation reaction of aromatic gem -difluoroalkenes was developed under the irradiation of blue light in dimethyl carbonate as a green solvent, leading to α,α-difluoroalkylthioethers in good yields. A photocatalyst-free hydrothiolation reaction of aromatic gem -difluoroalkenes was developed under the irradiation of blue light in dimethyl carbonate as a green solvent.
ISSN:1144-0546
1369-9261
DOI:10.1039/d4nj01571a