Efficient decomposition of a melamine-formaldehyde foam into melamine selective disconnection of bonds

The precise disconnection of one type of chemical bond in polymers realizes high-yield recovery of valuable chemicals. In this study, we demonstrate a sustainable and efficient strategy to selectively cleave the specific sp 3 C-sp 3 N bond of a thermoset melamine-formaldehyde foam, by which valuable...

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Veröffentlicht in:Green chemistry : an international journal and green chemistry resource : GC 2024-12, Vol.26 (24), p.1186-11865
Hauptverfasser: Yang, Chaohui, Li, Xinyu, Li, Hongyan, Wang, Chizhou, Xing, Qianqian, Jia, Xiaoliang, Cui, Xiaojing, Hou, Xianglin, Deng, Tiansheng
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Zusammenfassung:The precise disconnection of one type of chemical bond in polymers realizes high-yield recovery of valuable chemicals. In this study, we demonstrate a sustainable and efficient strategy to selectively cleave the specific sp 3 C-sp 3 N bond of a thermoset melamine-formaldehyde foam, by which valuable melamine of 99.5% purity was obtained with a yield of 95.3%. Decomposition of MFF into melamine of 99.5% purity via selective disconnection of an sp 3 C-sp 3 N bond with a yield of 95.3%.
ISSN:1463-9262
1463-9270
DOI:10.1039/d4gc04481a