APTES functionalization in SBA-15: the effect on SO capture and detection applications

The development of adsorbents for air pollutant remediation and effective monitoring is of interest. Then, the effect of the APTES functionalization ratio on the impact of the adsorption and detection of SO 2 molecules was evaluated. The higher APTES functionalization material (SBA-15_6.1APTES) show...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2024-07, Vol.53 (29), p.1228-12214
Hauptverfasser: Obeso, Juan L, López Cervantes, Valeria B, Flores, Catalina V, García-Carvajal, Celene, Garduño-Albino, Carlos E, Peralta, Ricardo A, Trejos, Víctor M, Huerta Arcos, L, Ibarra, Ilich A, Solis-Ibarra, Diego, Cordero-Sánchez, Salomón, Portillo-Vélez, Nora S, Esparza-Schulz, J. Marcos
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Zusammenfassung:The development of adsorbents for air pollutant remediation and effective monitoring is of interest. Then, the effect of the APTES functionalization ratio on the impact of the adsorption and detection of SO 2 molecules was evaluated. The higher APTES functionalization material (SBA-15_6.1APTES) shows a high uptake of 1.15 mmol g −1 at 0.001 bar and 298 K. Fluorescence, time-resolved photoluminescence, and quantum yield experiments revealed a turn-on effect specifically for SO 2 molecules, indicating high selectivity, suggesting host-to-guest energy transfer. Attractively, XPS measurement provided an understanding of the mechanism, suggesting hydrogen bonding and dipole-dipole interactions as the main interactions between SO 2 molecules and SBA-15_6.1APTES. DFT calculations were performed to confirm these interactions. Furthermore, this study highlights the application of SBA-15 materials with different amino modifications for SO 2 treatment and provides insight into the interaction mechanism using experimental techniques. SBA-15 functionalized with APTES enables the selective detection of the SO 2 molecule.
ISSN:1477-9226
1477-9234
DOI:10.1039/d4dt01283f