Boosting the cell voltage in biphasic flow batteries Galvani potential difference

Galvani potential differences between aqueous and organic phases of biphasic flow batteries can be utilized to boost the cell voltage by ca. 600 mV. This effect is demonstrated by comparing batteries utilizing three different solvents, trifluorotoluene, dichloroethane and propylene carbonate, with ferrocene and decamethyl ferrocene as model organic redox couples. Galvani potential differences between aqueous and organic phases can increase the cell voltage of biphasic flow batteries by 600 mV.