Synthesis of dispiro-orthoester an acetal oxo-carbenium ion

The first dispiro orthoester via a spiroacetal oxo-carbenium ion is presented. Oxidative dearomatization of phloretic esters results in a bifunctional electrophilic spiroacetal oxo-carbenium ion, which undergoes a double nucleophilic addition by diol delivering a range of unusual dispiro-orthoesters with an excellent diversity. The first dispiro orthoester via a spiroacetal oxo-carbenium ion is presented.