A SmI-mediated reductive cyclisation reaction using the trifluoroacetamide group as the radical precursor

A samarium( ii )-mediated reductive cyclisation reaction with the aminoketyl radical from the trifluoroacetamide group for synthesising 2-trifluoromethylindolines was developed. This reaction is the first example of using an acyclic amide group, which is considered difficult to react with SmI 2 , in...

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Veröffentlicht in:Organic & biomolecular chemistry 2024-03, Vol.22 (1), p.1988-1992
Hauptverfasser: Yoshioka, Kota, Iwasaki, Hiroki, Hanaki, Mako, Ito, Saho, Iwamoto, Yuzuha, Ichihara, Rio, Nambu, Hisanori
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