DIBAL-H-mediated -deacetylation of tertiary amides: synthesis of synthetically valuable secondary amines

DIBAL-H-mediated -deacetylation of tertiary amides: synthesis of synthetically valuable secondary amines

A rapid DIBAL-H-mediated N -deacetylation of tertiary amides is described under mild conditions, affording synthetically valuable secondary amines in good to excellent yields. Described herein is a general and practical DIBAL-H-enabled N -deacetylation reaction of tertiary amides to access important...

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Veröffentlicht in:Organic & biomolecular chemistry 2024-01, Vol.22 (3), p.51-55
Hauptverfasser: Shukla, Pushpendra Mani, Pratap, Aniruddh, Maji, Biswajit
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Zusammenfassung:A rapid DIBAL-H-mediated N -deacetylation of tertiary amides is described under mild conditions, affording synthetically valuable secondary amines in good to excellent yields. Described herein is a general and practical DIBAL-H-enabled N -deacetylation reaction of tertiary amides to access important N-heterocycles.
ISSN:1477-0520
1477-0539
DOI:10.1039/d3ob01660a