One-pot synthesis of 11-sulfenyl dibenzodiazepines tandem sulfenylation/cyclization of -isocyanodiaryl amines and diaryl disulfides
A one-pot sulfenylation/cyclization of o -isocyanodiaryl amines has been described for the preparation of 11-sulfenyl dibenzodiazepines. This AgI-catalyzed reaction covers an unexplored tandem process to give seven-membered N-heterocycles. This transformation shows a broad range of substrate scope,...
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| Veröffentlicht in: | Organic & biomolecular chemistry 2023-05, Vol.21 (2), p.4257-4263 |
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| container_title | Organic & biomolecular chemistry |
| container_volume | 21 |
| creator | Liu, Yi Gao, Wei Yuan, Sitian Ni, Mengjia Hao, Tianxin Zeng, Cuiying Xu, Xinyi Fu, Yang Peng, Yiyuan Ding, Qiuping |
| description | A one-pot sulfenylation/cyclization of
o
-isocyanodiaryl amines has been described for the preparation of 11-sulfenyl dibenzodiazepines. This AgI-catalyzed reaction covers an unexplored tandem process to give seven-membered N-heterocycles. This transformation shows a broad range of substrate scope, simple operation, and moderate to good yields under aerobic conditions. Diphenyl diselenide can also be produced in an acceptable yield.
AgI-catalyzed one-pot sulfenylation/cyclization of
o
-isocyanodiaryl amines has been described for the preparation of 11-sulfenyl dibenzodiazepines in moderate to good yields. |
| doi_str_mv | 10.1039/d3ob00220a |
| format | Article |
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-isocyanodiaryl amines has been described for the preparation of 11-sulfenyl dibenzodiazepines. This AgI-catalyzed reaction covers an unexplored tandem process to give seven-membered N-heterocycles. This transformation shows a broad range of substrate scope, simple operation, and moderate to good yields under aerobic conditions. Diphenyl diselenide can also be produced in an acceptable yield.
AgI-catalyzed one-pot sulfenylation/cyclization of
o
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-isocyanodiaryl amines has been described for the preparation of 11-sulfenyl dibenzodiazepines. This AgI-catalyzed reaction covers an unexplored tandem process to give seven-membered N-heterocycles. This transformation shows a broad range of substrate scope, simple operation, and moderate to good yields under aerobic conditions. Diphenyl diselenide can also be produced in an acceptable yield.
AgI-catalyzed one-pot sulfenylation/cyclization of
o
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-isocyanodiaryl amines has been described for the preparation of 11-sulfenyl dibenzodiazepines. This AgI-catalyzed reaction covers an unexplored tandem process to give seven-membered N-heterocycles. This transformation shows a broad range of substrate scope, simple operation, and moderate to good yields under aerobic conditions. Diphenyl diselenide can also be produced in an acceptable yield.
AgI-catalyzed one-pot sulfenylation/cyclization of
o
-isocyanodiaryl amines has been described for the preparation of 11-sulfenyl dibenzodiazepines in moderate to good yields.</abstract><doi>10.1039/d3ob00220a</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
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| ispartof | Organic & biomolecular chemistry, 2023-05, Vol.21 (2), p.4257-4263 |
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| source | Royal Society of Chemistry Journals Gold Package; Alma/SFX Local Collection |
| title | One-pot synthesis of 11-sulfenyl dibenzodiazepines tandem sulfenylation/cyclization of -isocyanodiaryl amines and diaryl disulfides |
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