Palladium-catalyzed domino cyclization/direct functionalization involving the insertion of SO

Palladium-catalyzed domino cyclization/direct functionalization involving the insertion of SO

A reductive cross-coupling strategy for the synthesis of sulfone-containing oxindoles via palladium-catalyzed domino cyclization/alkylsulfonylation reaction of N -substituted arylacrylamides with unactivated alkyl bromides and Na 2 S 2 O 5 is presented. Moreover, using amines instead of alkyl bromid...

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Veröffentlicht in:New journal of chemistry 2024-03, Vol.48 (12), p.511-516
Hauptverfasser: Zhang, Xinwei, Lu, Yaoyao, Zhang, Shuoshuo, Lin, Shuizhen, Chen, Mengting, Huang, Xiaolei
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container_issue 12
container_start_page 511
container_title New journal of chemistry
container_volume 48
creator Zhang, Xinwei
Lu, Yaoyao
Zhang, Shuoshuo
Lin, Shuizhen
Chen, Mengting
Huang, Xiaolei
description A reductive cross-coupling strategy for the synthesis of sulfone-containing oxindoles via palladium-catalyzed domino cyclization/alkylsulfonylation reaction of N -substituted arylacrylamides with unactivated alkyl bromides and Na 2 S 2 O 5 is presented. Moreover, using amines instead of alkyl bromides, a palladium-catalyzed domino cyclization/aminosulfonylation was also established. A reductive cross-coupling strategy for the synthesis of sulfone-containing oxindoles was presented. Moreover, using amines instead of alkyl bromides, a palladium-catalyzed domino cyclization/aminosulfonylation was also established.
doi_str_mv 10.1039/d3nj05872g
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title Palladium-catalyzed domino cyclization/direct functionalization involving the insertion of SO
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