Why does the cyclic pentazolate anion fail to undergo -oxidization in oxone solution?
When the pentazolate anion (cyclo-N 5 − ) was treated with oxone, a peak of m / z = 86 was detected via liquid chromatography mass spectrometry (LC-MS), which is the same molecular weight as the pentazolate N -oxide anion. After separation we obtained a completely new structure consisting of NaN 5 ,...
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| Veröffentlicht in: | New journal of chemistry 2023-03, Vol.47 (12), p.5616-562 |
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| container_issue | 12 |
| container_start_page | 5616 |
| container_title | New journal of chemistry |
| container_volume | 47 |
| creator | Xu, Ze Jiang, Shuaijie Hou, Tianyang Zhang, Xiaopeng Lu, Ming Xu, Yuangang |
| description | When the pentazolate anion (cyclo-N
5
−
) was treated with oxone, a peak of
m
/
z
= 86 was detected
via
liquid chromatography mass spectrometry (LC-MS), which is the same molecular weight as the pentazolate
N
-oxide anion. After separation we obtained a completely new structure consisting of NaN
5
, sodium acetate, and acetic acid with a confirmed molecular weight of 86 as an impurity peak in the oxone system.
The cyclo-pentazolate anion failed to be oxidized using oxone. How can this be realized? |
| doi_str_mv | 10.1039/d3nj00215b |
| format | Article |
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5
−
) was treated with oxone, a peak of
m
/
z
= 86 was detected
via
liquid chromatography mass spectrometry (LC-MS), which is the same molecular weight as the pentazolate
N
-oxide anion. After separation we obtained a completely new structure consisting of NaN
5
, sodium acetate, and acetic acid with a confirmed molecular weight of 86 as an impurity peak in the oxone system.
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5
−
) was treated with oxone, a peak of
m
/
z
= 86 was detected
via
liquid chromatography mass spectrometry (LC-MS), which is the same molecular weight as the pentazolate
N
-oxide anion. After separation we obtained a completely new structure consisting of NaN
5
, sodium acetate, and acetic acid with a confirmed molecular weight of 86 as an impurity peak in the oxone system.
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5
−
) was treated with oxone, a peak of
m
/
z
= 86 was detected
via
liquid chromatography mass spectrometry (LC-MS), which is the same molecular weight as the pentazolate
N
-oxide anion. After separation we obtained a completely new structure consisting of NaN
5
, sodium acetate, and acetic acid with a confirmed molecular weight of 86 as an impurity peak in the oxone system.
The cyclo-pentazolate anion failed to be oxidized using oxone. How can this be realized?</abstract><doi>10.1039/d3nj00215b</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1144-0546 |
| ispartof | New journal of chemistry, 2023-03, Vol.47 (12), p.5616-562 |
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| recordid | cdi_rsc_primary_d3nj00215b |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Why does the cyclic pentazolate anion fail to undergo -oxidization in oxone solution? |
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