Why does the cyclic pentazolate anion fail to undergo -oxidization in oxone solution?
When the pentazolate anion (cyclo-N 5 − ) was treated with oxone, a peak of m / z = 86 was detected via liquid chromatography mass spectrometry (LC-MS), which is the same molecular weight as the pentazolate N -oxide anion. After separation we obtained a completely new structure consisting of NaN 5 ,...
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Veröffentlicht in: | New journal of chemistry 2023-03, Vol.47 (12), p.5616-562 |
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Hauptverfasser: | , , , , , |
Format: | Artikel |
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Zusammenfassung: | When the pentazolate anion (cyclo-N
5
−
) was treated with oxone, a peak of
m
/
z
= 86 was detected
via
liquid chromatography mass spectrometry (LC-MS), which is the same molecular weight as the pentazolate
N
-oxide anion. After separation we obtained a completely new structure consisting of NaN
5
, sodium acetate, and acetic acid with a confirmed molecular weight of 86 as an impurity peak in the oxone system.
The cyclo-pentazolate anion failed to be oxidized using oxone. How can this be realized? |
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ISSN: | 1144-0546 1369-9261 |
DOI: | 10.1039/d3nj00215b |